+++статья Chem.Soc.Japan 72 (1951)

[Osmate Kate]

Доброго времени суток, коллеги!

Помогите, пожалуйста, найти статью:

Inamura Y. and Kondo Y. J. Chem.Soc.Japan 72 (1951) 787

Заранее огромное спасибо!

[aber]

Spectrochemical Studies on Iridium Complexes. I
Tervalent Iridium Complexes
Yasuo Inamura, Yukio Kondo
1951 Volume 72 Issue 9 Pages 787-789
Published: September 10, 1951
Released: February 05, 2009
DOIhttps://doi.org/10.1246/nikkashi1948.72.78
https://www.jstage.jst.go.jp/article/ni ... e/-char/en

[aber]

На всякий случай реферат из СА.

Spectrochemical studies on iridium complexes. I. Tervalent-​iridium. complexes
By: Inamura, Yasuo; Kondo, Yukio

Absorption spectra of six tervalent-​Ir complexes were measured in aq. soln.; all complexes have 3 absorption bands. In addn. to these bands the salts which contain pyridine show a special absorption band which shifted towards longer wave length compared with the band of pyridine itself. This means the unstabilization of pyridine mol. by coördination. The third absorption bands numbered from the longer wave length which are characteristic of the neg. radicals coordinated in the trans position are in 80-​100 × 1013 sec.-​1 and more bathochromic than those of many Co complexes which are in 120 × 1013. The first absorption bands have the relatively low extinction coeffs. log ε = 1.2 and arc shifted towards the longer wave lengths in the following order [IrCl6] > [IrCl4(C2O4)​] > [IrpyCl3 (C2O4)​] > [IrpyCl (C2O4)​2]​, [IrpyCl5] > [Irpy2Cl4]​.

[Osmate Kate]

спасибо большое!
буду учить японский)